Aquabis(o-vanillinato-κ2 O,O′)nickel(II)
نویسندگان
چکیده
The Ni(II) atom in the title complex, aqua-bis(2-formyl-6-meth-oxy-phenolato-κ(2)O,O')nickel(II), [Ni(C(8)H(7)O(3))(2)(H(2)O)], is five-coordinated by four O atoms from two o-vanillinate ligands and one water mol-ecule in a slightly distorted square-pyramidal geometry (τ = 0.06). In the crystal structure, the mol-ecules are linked into dimers by inter-molecular O-H⋯O hydrogen bonds.
منابع مشابه
cis-Aquabis(2,4-dichloro-6-formylphenolato-κ2 O,O′)(N,N-dimethylformamide-κO)nickel(II)
In the title compound, [Ni(C(7)H(3)Cl(2)O(2))(2)(C(3)H(7)NO)(H(2)O)], the Ni(II) ion is coordinated by four O atoms from two bidentate 2,4-dichloro-6-formyl-phenolate ligands, one O atom from a water ligand and one O atom from a dimethyl-formamide ligand in a slightly distorted octa-hedral environment. In the crystal structure, centrosymmetric dimers are formed though O-H⋯O and O-H⋯Cl hydrogen ...
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